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Catalyst suitability matrix

Which catalyst suits which reaction. A mark in a column means the reaction proceeds on that catalyst; conditions, loading, and selectivity are selected for each specific process.

Organic synthesis reaction Pd/C Pt/C Pt-Pd/C Ru/C
1. Saturation of aromatic hydrocarbons ✓
2. Hydrogenation of acetylene to alkanes ✓ ✓
3. Hydrogenation of aliphatic aldehydes to alcohols ✓
4. Aromatic aldehydes to aromatic alcohols ✓
5. Hydrogenation of aromatic aldehydes to aromatic alcohols ✓
6. Hydrogenation of carbocyclic aromatic hydrocarbons to cyclohexylamine ✓
7. Hydrogenation of aniline to dicyclohexylamine ✓ ✓
8. Hydrogenation of carbocyclic aromatic hydrocarbons to naphthenes ✓
9. Hydrogenation of gasoline compounds to aromatic hydrocarbons ✓
10. Reductive alkylation ✓
11. Reductive alkylation of chloroaniline ✓ ✓
12. Reductive alkylation of chloronitroaromatics ✓
13. Dehalogenation of aliphatic and aromatic halides ✓
14. Hydrogenation of hydrazone to hydrazine ✓ ✓
15. Hydrogenation to an amine ✓ ✓
16. Hydrogenation of aromatic ketones to aromatic alcohols ✓
17. Hydrogenation of aromatic ketones to aromatic hydrocarbons ✓
18. Hydrogenation of fatty nitrile to primary amines (R-NH₂) ✓ ✓
19. Hydrogenation of fatty nitrile to a tertiary amine (R₃N) ✓ ✓
20. Hydrogenation of aromatic nitrile to benzylamine ✓
21. Partial reduction of aromatic nitriles to aldehydes ✓
22. Hydrogenation of aromatic nitrile to dibenzylamine ✓
23. Hydrogenation of nitroaromatics to aniline ✓ ✓
24. Hydrogenation of nitroaromatics to aromatic hydroxylamines ✓ ✓
25. Hydrogenation of nitroaromatics to aminophenols ✓
26. Hydrogenation of olefins to alkanes ✓ ✓
27. Hydrogenation of oxime to an amine ✓
28. Hydrogenation of oxime to hydroxylamine ✓
29. Hydrolysis of ethylene oxide ✓
30. Hydrogenation of phenol ✓
31. Hydrogenation of pyridine to piperidine ✓
32. Hydrogenation of aromatic ketones to aliphatic alcohols ✓ ✓
33. Hydrogenation of aliphatic acids ✓
34. Hydroxylamine synthesis ✓ ✓
35. Hydrogenation of aliphatic ketones to alcohols ✓ ✓
36. Saturation of halovinyl compounds ✓ ✓
37. Saturation with propyl compounds ✓

Reactions listed: 37. Data is taken from the manufacturer's catalog and is confirmed during selection.

Catalysts

Pd/C

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Pt-Pd/C

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Pt/C

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Ru/C

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